A simple classical atom-atom model qualitatively explains the relative differential cross sections of chemi-ionization processes M + X2
M+ + (X + X-). However, there is still no reliable quantitative explanation
. A simple classical atom-atom model is not sufficient for the explanation of ion-pair formation in molecular collisions.}
It has already been found
that the total cross sections of collisions between Li or Na atoms and I atoms can be described using the Landau-Zener transition probability. The question is whether the differential cross section of such a simpler system can also be explained using the Landau-Zener model.
For a more detailed study the experimental resolution should be enhanced. Recently we have replaced the sputtering source
by a charge-exchange source
In the near future we shall determine the potential parameters of some alkali atom-halogen molecule potential curves by quantum-mechanical calculations and with the help of better resolved differential cross sections.